University of Liverpool - Sum Frequency Generation Group

Publications

Theses

• Nungnit Wattanavichean, Raman spectroscopy of molecular electronic junctions
• Takuma Omiya, Energy Conversion between CO and Porphyrins on Surfaces Studied by Ultrafast Vibrational and Scanning Tunneling Spectroscopies
• Sergio Mauri, Insulin unfolding and aggregation: a multi-disciplinary study
• Natalia Garcia-Rey, Interaction of a Copper Surface with Light: Plasmons, Electrons & Molecular Vibrations
This thesis has won the 2011 Woodruff thesis prize of the Thin Films and Surfaces group of the IOP.
• Ian Lane, Ultrafast Molecular Dynamics at Surfaces
• Jonathan Symonds, Femtosecond Sum-Frequency Spectroscopy of Metal-Adsorbate Systems

Publications

1. N. Garcia-Rey, H. Arnolds, "Ultrafast Dynamics of the dipole-moment reversal in a polar organic monolayer" J. Chem. Phys. accepted (2019)
2. T. Omiya, Y. Kim, R. Raval, H. Arnolds, "Ultrafast Vibrational Dynamics of CO Ligands on RuTPP/Cu(110) under Photodesorption Conditions" Surfaces 2 (2019) 117
3. N. Wattanavichean, M. Gilby, R.J. Nichols, H. Arnolds, "Detection of Metal-Molecule-Metal Junction Formation by Surface-Enhanced Raman Spectroscopy" Analytical Chemistry 91 (2019) 2644
4. N. Wattanavichean, E. Casey, R.J. Nichols, H. Arnolds, "Discrimination between hydrogen bonding and protonation in the spectra of a surface-enhanced Raman sensor" Phys. Chem. Chem. Phys. 20 (2018) 866
5. H. Arnolds, A. Kakoulli, K. Shah, E.Patterson, "Characterization of metal fatigue by optical second harmonic generation" Applied Physics Letters 111 (2017) 131901
6. N. Garcia-Rey, M. Sacchi, S. J. Jenkins, H. Arnolds, "Dipole-Moment Reversal in a Polar Organic Monolayer Probed by Sum and Difference Frequency Spectroscopy" J. Phys. Chem. C 212 (2017) 6692
7. T. Omiya, P. Poli, H. Arnolds, R. Raval, M. Persson, Y. Kim, "Desorption of CO from individual ruthenium porphyrin molecules on a copper surface via an inelastic tunnelling process" Chem. Comm. 53 (2017) 6148
8. S. Mauri, M. Volk, S. Byard, H, Berchtold, H. Arnolds, “Stabilization of Insulin by Adsorption on a Hydrophobic Silane Self- Assembled Monolayer” Langmuir 2015 Link
9. S. Mauri, T. Weidner, H. Arnolds, “The structure of insulin at the air/water interfaces: monomers or dimers?” Phys. Chem. Chem. Phys. 16 (2014) 26722 Link
10. T. Omiya, H. Arnolds, “Coverage dependent non-adiabaticity of CO on a copper surface” Journal of Chemical Physics 141 (2014) 214705 Link
11. N. Garcia-Rey, H. Arnolds, “Hot hole-induced dissociation of NO dimers on a copper surface” Journal of Chemical Physics 135 (2011) 224708 Link
12. H. Arnolds, “Vibrational Dynamics of adsorbates – Quo vadis?” Progress in Surface Science 86 (2011) 1 Link
13. H.Arnolds, M. Bonn,
    Ultrafast Surface Vibrational Dynamics, Surface Science Reports 65 (2010) 45 Link
14. F. Thibault-Starzyk, E. Seguin, M. Daturi, H.Arnolds, D. A. King,
    Real-Time Infrared Detection of Cyanide Flip on Silver-Alumina NOx Removal Catalyst, Science 324, 1048 (2009) Link
15. H.Arnolds, D. A. King, I. M. Lane,
    Inducing non-adiabatic effects through coadsorption: CO + NO on iridium, Chemical Physics 350, 94 (2008) Link
16. I. M. Lane, Z. P. Liu, D. A. King, H.Arnolds,
    Ultrafast vibrational dynamics of NO and CO adsorbed on an iridium surface, Journal of Physical Chemistry C 111, 14198 (2007) Link
17. I. M. Lane, D. A. King, H.Arnolds,
    The determination of an inhomogeneous linewidth for a strongly coupled adsorbate system, Journal of Chemical Physics 126, 024707 (2007) Link
18. I. M. Lane, D. A. King, Z. P. Liu, H.Arnolds,
    Real-time observation of nonadiabatic surface dynamics: The first picosecond in the dissociation of NO on iridium, Physical Review Letters 97, 186105 (2006) Link
19. V. L. Zhang, H. Arnolds, D. A. King,
    Hot Band excitation of CO/Ir{111} studied by broadband sum frequency generation, Surface Science 587, 102 (2005) Link
20. J. P. R. Symonds, H. Arnolds, D. A. King,
    Femtosecond pump-probe spectroscopy of CO on Ru{10-10}, from experimental and theoretical perspectives,
    Journal of Physical Chemistry B 108 , 14311-14315 (2004) Link
21. J. P. R. Symonds, H. Arnolds, V. L. Zhang, K. Fukutani, D. A. King,
    Broadband femtosecond sum frequency spectroscopy of CO on Ru{10-10} in the frequency and time domains,
    Journal of Chemical Physics 120,7158-7164 (2004). Link
22. H. Arnolds,
    Femtosecond laser-induced reactions with O-2 on Pt{111}.
    Surface Science 548, 151-156 (2004). Link
23. H. Arnolds, R. J. Levis, D. A. King,
    Vibrationally assisted DIET through transient temperature rise: the case of benzene on Pt{111}.
    Chemical Physics Letters 380, 444-450 (2003). Link
24. H. Arnolds, J. P. R. Symonds, V. L. Zhang, D. A. King,
    In situ characterization of ultrafast laser pulses for sum frequency surface studies.
    Review of Scientific Instruments 74, 3943-3946 (2003). Link
25. H. Arnolds, C. E. M. Rehbein, G. Roberts, R. J. Levis, D. A. King,
    Femtosecond near-infrared laser desorption of multilayer benzene on Pt{111}: A molecular Newton's cradle?
    Journal of Physical Chemistry B 104, 3375-3382 (2000).
    Link
26. H. Arnolds, C. E. M. Rehbein, G. Roberts, R. J. Levis, D. A. King,
    Femtosecond near-infrared laser desorption of multilayer benzene on Pt{111}: spatial origin of hyperthermal desorption.
    Chemical Physics Letters 314, 389-395 (1999). Link
27. H. D. Ebinger, H. Arnolds, C. Polenz, B. Polivka, W. Preyb , D. Fick, H. J. Jänsch,
    Adsorption and diffusion of Li on an Ru(001) surface: an NMR study. Surface Science 412-413, 586-615 (1998). Link
28. H. Arnolds, D. Fick, H. Unterhalt, A. Voss, A. H. J. Jänsch,
    Particle detected Fourier transform NMR at single crystal surfaces - Li-6 on Ru(001).
    Solid State Nuclear Magnetic Resonance 11, 87-102 (1998).
    Link
29. H. Arnolds and H. J. Jänsch,
    Fourier transform NMR at single crystal surfaces - Li-6 on Ru(001).
    Chemical Physics Letters 272, 13-17 (1997). Link
30. H. J. Jänsch, H. Arnolds, H. D. Ebinger, C. Plenz, B. Polivka, G. J. Pietsch, W. Preyb , V. Saier, R. Veith and D. Fick,
    Coverage Dependence of the Local-Density of States at the Fermi Energy - Li Adsorbed on Ru(001). Link